53 questions · 34 almanac · 0 findings

Spectroscopy

Analyzing matter through its interaction with light.

Almanac A Magnet Reaches Inside the Atom
  • What did Pieter Zeeman actually see happen to the sodium spectral lines when he applied a magnetic field?
  • How did Hendrik Lorentz explain the splitting of spectral lines in terms of charged particles inside the atom?
  • What later technologies trace their roots back to the Zeeman effect?
Almanac Atoms Turned Out to Have Insides
  • Why did many contemporaries initially dismiss the Zeeman effect as just an optical anomaly?
  • How does the Zeeman effect connect to the technology behind modern MRI scanners?
Almanac Light Too Blue for Human Eyes
  • What electron transitions in hydrogen produce the ultraviolet lines of the Lyman series?
  • How does the Lyman series differ from the Balmer and Paschen series of hydrogen's spectral lines?
  • How did Niels Bohr's 1913 atomic model later explain the regular pattern Lyman had observed in 1908?
  • How do astronomers use Lyman series lines today to study hydrogen gas across the universe?
Almanac Every Element Has Its Own Signature
  • What did Barkla discover about the secondary X-rays that different elements emit when struck by primary radiation?
  • How did Barkla's mapping of characteristic X-rays give chemists a non-destructive way to identify elements?
Almanac Sound Physics From an Unsound Man
  • How did Johannes Stark demonstrate the Doppler shift in fast-moving canal rays in the laboratory?
  • What is the Stark effect, and how does a strong electric field split an atom's spectral lines?
  • How did Stark's later career as a National Socialist official and denouncer of Einstein's physics complicate his scientific legacy?
Almanac Neon's Awkward Decimal, Explained
  • Why did neon's atomic weight of 20.2 puzzle chemists before Aston's work?
  • How did Aston's mass spectrograph reveal that neon was a mixture of two isotopes?
Almanac Mapping the Atom, Decimal by Decimal
  • How did Manne Siegbahn improve X-ray spectrometers to measure wavelengths with such extreme precision?
  • Why did precise X-ray wavelength measurements matter for testing quantum theories of atomic structure?
  • What is characteristic radiation, and what does it reveal about the electron shells of an element?
Almanac One Photon in Ten Million, Shifted
  • Why does a tiny fraction of light change wavelength when it passes through a transparent material?
  • How can the wavelength shift of scattered light act as a fingerprint for identifying a molecule?
  • What equipment did Raman actually use to detect the effect that bears his name?
  • What modern applications rely on Raman spectroscopy today?
Almanac A Crack in Dirac's Perfect Equation
  • What discrepancy did Willis Lamb find between Dirac's equation and the measured energy levels of hydrogen?
  • What wartime radar technology let Lamb make microwave measurements precise enough to catch the Lamb shift?
Almanac Protons Have Shape, Crystals Hold Still Time
  • Why does absorbing a gamma ray inside a crystal lattice avoid the recoil that would normally blur a single free nucleus's emission?
  • How was the Mössbauer effect sensitive enough to detect the gravitational redshift predicted by general relativity using a source moved only a few feet?
Almanac Herding Atoms With Light
  • Why is optical pumping considered non-destructive compared to other ways of probing atomic structure?
Almanac An Atlas of Things That Vanish in Microseconds
  • What makes free radicals so difficult to study directly in a laboratory?
  • How did Gerhard Herzberg use spectroscopy to determine the geometry and electronic structure of short-lived molecules?
  • Why did Herzberg have to flee Germany, and how did he end up at Canada's National Research Council?